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刘志刚

发布于:2018-01-04 星期四 21:28:07 点击数:5832

博士、教授、博士生导师

E-mail: liuzhigang@hnu.edu.cn




基本信息

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刘志刚,Zhigang Liu

湖北鄂州

博士、教授、博士生导师

科研院院长助理(院聘)、化学系二支部书记、化学系副系主任

湖南省化学化工学会理事

湖南省催化与绿色化学专业委员会秘书长

教授本科生课程《有机化学》和硕士研究生课程《文献检索与科技论文写作。参与《有机化学》和《基础有机实验》精品课程建设,以及《有机化学》教材修订等工作。

近年来在仿生催化和碳催化以及稀土基催化剂等方向进行了深入研究,已发表50余篇科技论文,申请专利11项,授权专利5项。

本课题组有良好的科研实验条件和融洽的学术氛围,

欢迎有志于环保、能源和绿色化学事业的同学加盟!


教育背景

1995.09-1999.06  中国石油大学(华东)炼制系  学士学位

1999.09-2002.06  中国石油大学(北京)化学化工学院 硕士学位

2004.03-2007.03  浙江大学化学系  博士学位



工作履历

2011.03-2012.03  美国田纳西大学化学系 访问学者

2002.09-2003.06 清华大学化学系 访问学者

2007.05-2008.06   湖南大学化学化工学院  讲师

2008.06-2017.12   湖南大学化学化工学院  副教授

2017.12-至今         湖南大学化学化工学院  教授


学术兼职

中国化学学会会员

中国化工学会会员

湖南省化学化工学会理事

湖南省催化与绿色化学专业委员会秘书长

JACS、ACS Catalysis、Applied Catalysis B: EnvironmentACS Applied materials & interfaces、Chemical Communications、Catalysis Science & TechnologyChemical Engineering JournalIndustrial & Engineering Chemistry Research、化学学报等20余种国国内外学术期刊审稿人。

Frontiers in Chemistry :Carbon Catalysis专辑客座编辑

科技部科技项目、国家自然科学基金、广东省自然科学基金、浙江省自然科学基金、河北省自然科学基金、湖南省自然科学基金和科技计划项目等基金项目评审专家。

湖南省科技计划重点项目和重大项目验收专家。

长沙市工业科技特派员等。



研究领域

a. 仿生催化方向(碳催化剂制备及其催化机理研究)M-N-C.png

模拟生物酶的结构特点,结合新材料合成技术,将活性分子(如卟啉、M-N-C等)固载在特定形状的载体空间位置内,通过空间择形,改善催化剂在分子氧催化氧化烃类反应中活化C-HC-C键的性能,相关的碳材料也广泛应用于电池电极制备。



b.能源和环境催化方向(稀土基纳米催化剂的研究及其应用)稀土.png

以稀土金属催化剂为基础,结合纳米制备技术,以提高纳米金属催化剂的催化性能;并研究纳米催化剂催化氧化机理,尤其是反应过程中活性氧的来源和迁移路径等,相关催化剂广泛应用于室内污染、汽车尾气和电厂尾气等污染源的治理。


科研项目

目前主持在研或结题的项目有国家自然科学基金2项,湖南省自然基金1项,重质油加工国家重点实验室开放基金3项,中科院矿物学与成矿学重点实验室开放基金1项,湖南大学引进人才科研启动基金和湖南大学青年教师成长计划等科研项目等。曾参与研究的科研项目有国家973项目《稀土-多孔催化材料的组装及其在有机废气净化中的作用》,国家自然基金《尺寸可调纳米氧化锆的化学制备、表征及催化应用》以及中石油科研基金、美国自然科学基金、湖南省科技计划等项目。

学术成果

主要的专利和学术论文有:

专利:

刘志刚;黄芬芬;宋媛媛;王晓;孟德水;郭翔;黄程;曹驰;一种暖风型室内空气处理器, ZL201020572292.3(已授权)

刘志刚;郭翔;沈丹华; CeO2掺杂的有机硅纳米微球负载金属钴(ii)卟啉催化剂的制备ZL201010236927.7(已授权)

刘志刚;许愉梓;严大峰;戴明;姜丹丹;骆星宇;彭瑞资;叶子健;一种实验室废液分类回收装置 ZL201320144616.7(已授权)

刘志刚;刘岚;张帅;叶子健;一种带状水膜空气净化器 ZL 201320314570.9(已授权)

刘志刚;吉琳韬;刘佳;汪秋安;二氧化硅微球固载纳米金属化合物催化剂制备方法与应用CN201310715000.5(已授权)

刘志刚;李源;李坤;张雨燕;陶倩倩;郭永嘉;仿生纳米水空气净化器 ZL 201720520668.8 (已授权)

学术论文:

51. Shanshan Jie, Congqian Yang, Yuan Chen, Zhigang Liu*, Facile synthesis of ultra-stable Co-N-C catalysts using cobalt porphyrin and peptides as precursors for selective oxidation of ethylbenzene, Molecular Catalysis, 458 (2018), 1–8

50. Yuan Li, Shanshan Jie, Kun Li, Zhigang Liu*, Synthesis of efficient Co and N-co-doped carbon catalysts with high surface areas for selective oxidation of ethylbenzene, New Journal of Chemistry, 42 (2018), 12677–12683

49. Shanshan Jie, Xiu Lin, Qingze Chen, Runliang Zhu, Liyun Zhang, Bingsen Zhang, Zhigang Liu*, Montmorillonite-Assisted Synthesis of Cobalt-Nitrogen-Doped Carbon Nanosheets for High-Performance Selective Oxidation of Alkyl Aromatics, Applied Surface Science, 456 (2018), 951–958

48. Xiu Lin, Shanshan Jie, Zhigang Liu*, Sulfur and nitrogen-doped porous cobalt carbon catalyst for high efficient aerobic oxidation of hydrocarbons, Molecular Catalysis, 455 (2018), 143–149

47. Kun Li, Shanshan Jie, Yuan Li, Xiu Lin, Zhigang Liu*, The synthesis of N, S-codoped ordered mesoporous carbon as an efficient metal-free catalyst for selective oxidation of arylalkanes, Catalysis Communications, 112 (2018), 39–42

46. Shanshan Jie, Xiu Lin, Zisheng Chao*, Zhigang Liu*, Effective ternary copper-cerium-cobalt catalysts synthesized via a modified pechini method for selective oxidation of ethylbenzene, Materials Chemistry and Physics, 214 (2018), 239-246

45. Weiqing Kong, Kangkang Yao, Xidong Duan, Zhigang Liu*, Jiawen Hu*, Holey Co, N-codoped graphene aerogel with in-plane pores and multiple active sites for efficient oxygen reduction, Electrochimica Acta, 269 (2018), 544-552

44. Shi Feng, Xingyue Li, Jia Huo*, Qiling Li, Xie Chao, Tingting Liu, Zhigang Liu, Zhenjun Wu*, Shuangyin Wang*, controlled synthesis of CoS2@N/S-Codoped porous carbon derived from ZIF-67 for as a highly efficient catalyst for the hydrogen evolution reaction, ChemCatChem, 10(2018), 796-803

43. Shanshan Jie, Yuan Chen, Congiang Yang, Xiu LinRunliang Zhu, Zhigang Liu*, Co-N-C catalysts supported on mesoporous carbon with tailorable pore sizes for selective oxidation of arylalkanes, Catalysis Communications, 100 (2017), 144-147

42. Congqiang Yang, Shanshan Jie, Runliang Zhu*, Naidong Zhang, Jiqian Wang*, Zhigang Liu*, Co-N-C Catalysts Synthesized via Pyrolyzing the Ionic Liquids Solution Dissolved with Casein and Cobalt Porphyrin for Ethylbenzene Oxidation, ChemistySelect, 15 (2017), 4255-4260

41. Yuan Chen, Shanshan Jie, Congqiang Yang, Zhigang Liu, Active and efficient Co-N/C catalysts derived from cobalt porphyrin for selective oxidation of alkylaromatics, Applied Surface Science, 419 (2017) , 98–106

40. Xiu LinSufang ZhaoLingling FuYongming LuoRunliang Zhu*, Zhigang Liu*, Synthesis of Co-N-C grafted on well-dispersed MnOx-CeO2hollow mesoporous sphere with efficient catalytic performance, Molecular Catalysis, 437 (2017), 18-25

39. Xiu Lin, Zhenzhen Nie, Liyun Zhang, Shuchuan Mei, Yuan Chen, Bingsen Zhang,* Runliang Zhu, Zhigang Liu*, Nitrogen-doped carbon nanotubes encapsulate cobalt nanoparticles as efficient catalysts for aerobic and solvent-free selective oxidation of hydrocarbons, Green Chemistry, 19(2017), 2164-2173

38. Lei Xu, Zhimin Wang, Jialu Wang, Zhaohui Xiao, Xiaobing Huang, Zhigang Liu and Shuangyin Wang*, N-doped nanoporous Co3O4 nanosheets with oxygen vacancies as oxygen evolving electrocatalysts, Nanotechnology, 28 (2017), 165402-165410

37. Xiu Lin, Lingling Fu, Yuan Chen, Runliang Zhu, Shuangyin Wang, Zhigang Liu*, Mn–N-C Nanoreactor Prepared through Heating Metalloporphyrin Supported in Mesoporous Hollow Silica Spheres, ACS Applied Materials & Interfaces, 8 (2016), 26809-26816

36. Dafeng Yan, Shuo Dou, Li Tao, Zhijuan Liu, Zhigang Liu, Jia Huo and Shuangyin Wang*, Electropolymerized supermolecule derived N, P codoped carbon nanofiber networks as a highly efficient metal-free electrocatalyst for the hydrogen evolution reaction, Journal of Materials Chemistry A, 4 (2016), 13726-13730

35. Yuyuan Qiu, Congqiang Yang, Jia Huo, Zhigang Liu*, Synthesis of Co-N-C immobilized on carbon nanotubes for ethylbenzene oxidation, Journal of Molecular Catalysis A: Chemical, 420 (2016), 276-282

34. Congqiang Yang, Yuan Chen, Sufang Zhao, Runliang Zhu, Zhigang Liu*, Preparation of CoNC Catalysts via Heating the Mixture of Cobaltporphyrin and Casein for Ethylbenzene Oxidation, RSC Advances, 6 (2016), 75707-75714

33. Yuan Chen, Lingling Fu, Zhigang Liu*, Yong Wang*, Ionic-Liquid-Derived Boron-Doped Cobalt-Coordinating Nitrogen-Doped Carbon Materials for Enhanced Catalytic Activity, ChemCatChem, 8 (2016), 1782-1787

32. Xiu Lin, Sufang Zhao, Yuan Chen, Lingling Fu, Runliang Zhu, Zhigang Liu*, Nitrogen-doped carbon cobalt grafted on graphitic carbon nitride catalysts with enhanced catalytic performance for ethylbenzene oxidation, Journal of Molecular Catalysis A: Chemical, 420 (2016), 11-17

31. Lingling Fu, Sufang Zhao, Yuan Chen, Zhigang Liu*, One-pot synthesis of mesoporous silica hollow spheres with Mn–N–C integrated into the framework for ethylbenzene oxidation, Chemical Communications, 52(2016), 5577-5580

30. Lingling Fu, Yijuan Lu, Zhigang Liu*, Runliang Zhu, Influence of the metal sites of M-N-C (M = Co, Fe, Mn ) catalysts derived from metalloporphyrins in ethylbenzene oxidation, Chinese Journal of Catalysis, 37 (2016), 398-404

29. Lingling Fu, Yuan Chen, Sufang Zhao, Zhigang Liu*, Runliang Zhu*, Sulfur-mediated synthesis of N-doped carbon supported cobalt catalysts derived from cobalt porphyrin for ethylbenzene oxidation, RSC Advances, 6 (2016), 19482-19491

28. Congqiang Yang, Lingling Fu, Runliang Zhu, Zhigang Liu*, Influence of cobalt species on the catalytic performance of Co-N-C/SiO2 for ethylbenzene oxidation, Physical Chemistry and Chemical Physics, 18 (2016), 4635-4642

27. Yuan Chen, Lingling Fu, Zhigang Liu*, One-pot Synthesis of Cobalt-coordinated N-doped Carbon Catalysts via Co-synthesis of Ionic Liquid and Cobalt Porphyrin, Chemical Communications, 51 (2015), 16637 -16640

26. Lingling Fu, Yuan Chen, Zhigang Liu*, Cobalt catalysts embedded in N-doped carbon derived from cobalt porphyrin via a one-pot method for ethylbenzene oxidation, Journal of Molecular Catalysis A: Chemical, 408 (2015), 91-97

25. Shupanxiang Chen, Sufang Zhao, Zhen Xu, Zhigang Liu*, Runliang Zhu, Influence of pH on the catalytic performance of CuO-CoOx-CeO2 for CO oxidation, RSC Advances, 5 (2015), 61735-61741

24. Yuan Chen, Sufang Zhao, Zhigang Liu*, Influence of the synergistic effect between Co-N-C and ceria on the catalytic performance for selective oxidation of ehtylbenzene, Physical Chemistry and Chemical Physics, 17 (2015), 14012-14020

23. Sufang Zhao, Yuan Chen, Zhigang Liu*, Immobilization of metalloporphyrin on silica shell with bimetallic oxide core for ethylbenzene oxidation, RSC Advances, 5 (2015), 33299-33305

22. Dan-Hua Shen, Lin-Tao Ji, Ling-ling Fu, Xu-long Dong, Zhi-Gang Liu*, Qiang Liu, Shi-ming Liu, Immobilization of metalloporphyrins on CeO2@SiO2 with a core-shell structure prepared via microemulsion method for catalytic oxidation of ethylbenzene, Journal of Central South University, 22 (2015), 862-867

21. Zhigang Liu*, Lintao Ji, Xulong Dong, Zhen Li, Lingling Fu, Qiuan Wang, Preparation of Co-N-C supported on silica spheres with high catalytic performance for ethylbenzene oxidation, RSC Advances, 5 (2015), 6259-6264

20. Zhi-Gang Liu*, Zi-Li Wu*, Xi-Hong Peng, Andrew Binder, Song-Hai Chai, Sheng Dai*, Origin of active oxygen in a ternary CuOx/Co3O4-CeO2 catalysts for CO oxidation, Journal of Physical Chemistry C, 118 (2014), 27870-27877

19. Zhi-Gang Liu*, Lin-Tao Ji, Jia Liu, Ling-Ling Fu, Su-Fang Zhao, Influence of heat treatment on catalytic performance of Co-N-C/SiO2 for selective oxidation of ehtylbenzene, Journal of Molecular Catalysis A: Chemical, 395 (2014), 315-321.

18. Dan-Hua Shen, Lin-Tao Ji, Zhi-Gang Liu*, Wen-Bin Sheng, Can-Cheng Guo**, Ethylbenzene oxidation over hybrid metalloporphyrin@silicananocomposite microspheres, Journal of Molecular Catalysis A: Chemical, 379 (2013), 15-20.

17. Zhi-Gang Liu*, Song-Hai Chai, Andrew Binder, Sheng Dai*, Influence of calcination temperature on the structure and catalytic performance of CuOx-CoOy-CeO2 ternary mixed oxide for CO oxidation, Applied Catalysis A: General, 451 (2013) 282-288.

16. Xiang Guo, Yuan-Yuan Li, Dan-Hua Shen, Jie Gan, Yuanyuan Song, Xiao Wang, Zhi-Gang Liu*, Immobilization of Metalloporphyrins on CeO2@SiO2 Core-shell Nanoparticles as A Novel Catalyst for Selective Oxidation of Diphenylmethane, Journal of Molecular Catalysis A: Chemical, 367 (2013), 7-13.

15. Xiang Guo, Yuan-Yuan Li, Dan-Hua Shen, Jie Gan, Mi Tian, Zhi-Gang Liu*, Metalloporphyrins immobilized on core–shell CeO2@SiO2 nanoparticles prepared by a double-coating method for oxidation of diphenyl methane, Applied Catalysis A: General, 413-414 (2012), 30-35.

14. Yang Xiao, Xiaoyan Zhang, Qinbo Wang, Ze Tan, Cancheng Guo *, Wei Deng, Zhigang Liu, Hefei Zhang, The preparation of terephthalic acid by solvent-free oxidation of p-xylene with air over T( p-Cl)PPMnCl and Co(OAc)2, Chinese Chemical Letters, 22 (2011), 135–138

13. Xiang Guo, Dan-Hua Shen, Yuan-Yuan Li, Mi Tian, Qiang Liu, Can-Cheng Guo, Zhi-Gang Liu*, Immobilization of metalloporphyrin on organosilicon microsphere mixed with ceria as a new catalyst for oxidation of cyclohexane, Journal of Molecular Catalysis A: Chemical, 351 (2011), 174-178.

12. Zhigang Liu, Yunlong Xie, Wensheng Li, Renxian Zhou, Xiaoming Zheng, Influence of reduction energy match among CuO species in CuO-CeO2 catalysts on the catalytic performance for CO preferential oxidation in excess hydrogen, Journal of Natural Gas Chemistry, 20 (2011), 111-116.

11. Zhigang Liu, Shuren Yang, Renxian Zhou, Xiaoming Zheng, Influence of pH values in the preparation of CuO-CeO2 on its catalytic performance for the preferential oxidation of CO in excess hydrogen, Journal of Natural Gas Chemistry, 19 (2010), 313-317.

10. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Influence of residual K+ on the catalytic performance of CuO-CeO2 catalysts in preferential oxidation of CO in excess hydrogen, International Journal of Hydrogen Energy, 33 (2008), 791-796.

9. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Influence of Ethanol washing in Precursor on CuO-CeO2 catalysts in preferential oxidation of CO in excess hydrogen, Catalysis Letters, 123 (2008), 102-106.

8. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Preferential oxidation of CO in excess hydrogen over a nanostructured CuO-CeO2 catalyst with high surface area, Catalysis Communications, 9 (2008), 2183-2186.

7. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Influence of rare-earth metal doping on the catalytic performance of CuO-CeO2 for the preferential oxidation of CO in excess hydrogen, Journal of Natural Gas Chemistry, 17(2008), 283-287.

6. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Influence of preparation methods on CuO-CeO2 catalysts in the preferential oxidation of CO in excess hydrogen, Journal of Natural Gas Chemistry, 17(2008), 125-129.

5. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Preferential Oxidation of CO in Excess Hydrogen over CuO-CeO2 Catalyst Prepared by Chelating Method, Journal of Natural Gas Chemistry, 16(2007), 167-172.

4. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, Comparative study of different methods of preparing CuO-CeO2 catalysts for preferential oxidation of CO in excess hydrogen, Journal of Molecular Catalysis A: Chemical, 267 (2007), 137-142.

3. Zhigang Liu, Renxian Zhou, Xiaoming Zheng, The preferential oxidation of CO in excess hydrogen: A study of the influence of KOH/K2CO3 on CuO-CeO2-x catalysts, Journal of Molecular Catalysis A : Chemical, 255 (2006), 103-108.

2. 郑淑琴,甘杰,任劭,刘志刚,姚华,以Si-Al凝胶、高岭土水热晶化合成多级孔道催化材料,石油学报(石油加工), 30(2014), 32-37

1.  刘志刚, 周仁贤, 郑小明, 过渡金属修饰对铜铈催化剂在选择性脱除CO反应中催化性能的影响, 浙江大学学报(理学版), 36(2009), 299-303.



奖励与荣誉

湖南省化学化工学会先进个人(2018)

湖南大学创新创业优秀指导教师(2018)

全国化工年会优秀论文 (2017)

湖南大学优秀班主任 (2017)

化学化工学院优秀教师(2017)

化学化工学院优秀班主任 (2016)

湖南大学青年教师讲课比赛三等奖 (2015)

化学化工学院优秀教师  (2014)

已指导50多人次的本科生参加课外科技活动,并受到多项获得国家级、重点和面上SIT项目的支持,获得第二、第四届全国高校环保科技创意设计大赛和第十届 “挑战杯”湖南省大学生课外科技作品竞赛等多项奖项。截止目前,在本课题组参加课外科技活动的本科生,大多都保送研究生或出国深造。

本课题组已培养研究生十多人。近年来,课题组研究生多人获得过一等奖学金奖励,并多次获得优秀研究生、优秀研究生干部和优秀毕业生等称号,其中,陈远、林秀、揭山山等研究生获得了国家奖学金,付玲玲等同学的毕业论文还被评为湖南大学优秀硕士论文。


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近年来课题组研究生科研成果汇总表

姓名

入学时间

本科学校

文章和专利

荣誉称号

吉琳韬

2011

湖南师大

RSC Adv.(2015)J. Mol. Catal.   A(2014)、中国发明专利:CN201310715000.5


付玲玲

2013

山东理工

Chem. Comm.(2016), RSC Adv.(2016)Chin. J. Catal.   (2016), J. Mol. Catal. A(2015)

一等奖学金、湖南大学优秀硕士论文、湖南省优秀硕士论文

赵素芳

2013

河南理工

RSC Adv. (2015), RSC Adv.(2015)

一等奖学金

陈远

2014

桂林理工

PCCP(2015), ChemCatChem(2016), Chem.   Comm.(2016), Appl. Surf. Sci.(2017)

优秀研究生干部、国家奖学金、一等奖学金、湖南大学优秀硕士论文

杨从强

2014

黄冈师范

PCCP(2016), RSC Adv.(2016), Chem.   Selct.(2017)

一等奖学金

林秀

2015

湖南科技

Mol. Catal.(2018),Green chem.(2017), Mol. Catal.(2017), ACS Appl. Mater. Interface2016, J. Mol. Catal. A(2016)

国家奖学金、一等奖学金、化工学院科技之星

揭山山

2016

江西师大

New J. Chem.(2018), Catal. Comm.(2018), Appl. Surf. Sci.(2018), Mol. Catal.(2018), Mater. Chem. Phys.(2018), Catal. Comm.(2017)

国家奖学金、优秀研究生、一等奖学金

谌春

2017

武汉科技



小灿

2017

南工程



张露霜2018重庆师大