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许新华

发布于:2018-02-02 星期五 17:27:07 点击数:5096

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基本信息

男,1964年11月出生,博士,教授,博士生导师。 1991年获湖南师范大学有机化学硕士学位;1998年获杭州大学有机化学专业博士学位,从事有机合成方法和金属有机化学研究,师从黄宪院士;1998.6-2000.6在南开大学元素有机国家重点实验室进行药物化学博士后研,合作老师为陈茹玉院士;2000年6月至今在湖南大学化学化工学院工作;2002年度在日本Okayama 大学进行博士后研究。近几年主持国家自然科学基金和部省级科研项目10余项;作为通信联系人在国际重要刊物J. Org. Chem., Org. Lett., Adv. Synth. Catal. Green Chem.,Chem.Commun.等权威刊物及SCI原刊发表论文120余篇,申请发明专利41项。培养硕士生80余名,博士生10名。


教育背景

1981.9-1984.6,湖南邵阳师范专科学校化学科学习。

1988.9-1991.6,湖南师范大学化学系有机专业硕士生,指导老师:俞善信教授。

1995.9-1998.6,杭州大学化学系有机化学专业博士生,指导老师:黄宪院士。

1998.9-2000.6,南开大学元素所药物化学专业博士后,合作老师:陈茹玉院士。

2002年度在日本冈山理工大学应用研究所从事超分子研究。


工作履历

1984.6-1988.8,湖南武冈泉塘乡中学、武冈头桥区中学担任初中、高中化学教学。

1991.6-1995.8,湖南农学院基础部担任本科《有机化学》理论、实验教学。

2000.6-至今, 湖南大学化工学院担任本科《有机化学》理论、实验教学;担任硕士生《金属有机》、《元素有机》、《超分子化学》教学。


科研项目

1、国家自然科学基金面上项目对水稳定的金属Lewis acid研制与应用研究 2004.1-2006.12

2国家自然科学基金面上项目对空气稳定的新颖的有机金属Lewis acid制备、表征及应用研究, 2012.1-2013.12

3、国家自然科学基金面上项目新型有机铯配合物合成、表征及其在碳-杂键形成反应中的催化应用研究2013.1-2016.12

4、国家自然科学基金重点项目:“化学溶剂吸收法捕获二氧化碳过程降低热能消耗关键科学问题研究”子课题“新型有机胺合成研究”负责人, 2016.1-2020.12 

5、湖南省重大科技专项4- ADl绿色生物合成与甾体类药物研发子课题度他雄胺原料药注册申报及原料药产业化研究负责人,2014.6-2017.6

 


学术成果

近5年发表论文:

[1] Linghui Lu, Sijia Zhou, Meng Sun, Jialiang Chen, Wen Xia, Xianyong Yu, Xinhua Xu*, and Wei-Min He*, Metal- and Solvent-Free Ultrasonic Multicomponent Synthesis of (Z)-β-Iodo Vinylthiocyanates, ACS Sustainable Chem. Eng., 7 (1), 1574–1579, 2019.(IF=6.140)

[2] Yanxia Nan, Wenjie Zhao*, Ningbo Li, Zhiwu Liang*, Xinhua Xu*, Chemiluminescence-triggered fluorophore release: Approach for in vivo fluorescence imaging of hydrogen peroxide, Sensors & Actuators: B. Chemical., 281, 296–302, 2019.(IF=5.667)

[3] Zheng‐Jun Wang , Jing‐Jing Lv, Rong‐Nan Yi, Min Xiao, Jiu‐Ju Feng, Zhi‐Wu Liang*,  Ai‐Jun Wang*, Xinhua Xu*, Nondirecting Group sp3 C−H Activation for Synthesis of Bibenzyls via Homo‐coupling as Catalyzed by Reduced Graphene Oxide Supported PtPd@Pt Porous Nanospheres, Adv. Synth. Catal., 360, 932–941, 2018.(IF=5.123)

[4] Ningbo Li, Lingxiao Wang, Liting Zhang, Wenjie Zhao, Jie Qiao, Xinhua Xu*, Zhiwu Liang, Air‐stable Bis(pentamethylcyclopentadienyl) Zirconium Perfluorooctanesulfonate as an Efficient and Recyclable Catalyst for the Synthesis of N‐substituted Amides, Chem.Cat.Chem., 10, 3532, 2018.(IF=4.674)

[5] Ling-Hui Lu, Si-Jia Zhou,  Wei-Bao He,  Wen Xia,  Ping Chen,  Xianyong Yu,  Xinhua Xu*  and  Wei-Min He*, Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature, Org. Biomol. Chem., 16, 9064, 2018.(IF=3.423)

[6] Rongnan Yi, Jinyang Chen, Xueyan Wang, Zhiwu Liang*, Xinhua Xu*,A Rapid and Highly Efficient Method for the Synthesis of Benzofulvenes via CsOH‐Catalyzed Condensation of Indene and Aldehydes, Eur.J.Org.Chem., 11, 1347–1351, 2018.(IF=2.882)

[7] Ningbo Li, Lingxiao Wang, Haojiang Wang, Jie Qiao, Zhiwu Liang, Wenjie Zhao*, Xinhua Xu*, Synthesis and structure of an air-stable bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate and its application in catalytic epoxide ring-opening reactionsTetrahedron, 74, 1033-1039, 2018.(IF=2.377)

[8] Xiaohong Zhang, Xinhua Xu*, Ningbo Li, Zhiwu Liang*, Zilong Tang, Air-stable μ2-hydroxyl bridged cationic binuclear complexes of zirconocene perfluorooctanesulfonates: their structures, characterization and application, Tetrahedron, 74, 1926-1932, 2018.(IF=2.377)

[9] Ningbo Li, Jiao Yao, Lingxiao Wang, Jiancong Wei*, Wen Liu, Wenqi Liu*, Xinhua Xu*, Zhiwu Liang,Titanocene perfluorobutanesulfonate catalyzed reduction of disulfides in the presence of zinc to synthesize unsymmetrical sulfides, Inorganic Chemistry Communication., 98, 99−104, 2018.(IF=1.810)

[10]  Zhi Tang, Qiutao Jiang, Lifen Peng, Xinhua Xu*, Jie Li*, Renhua Qiu* and Chak-Tong Au, Zirconocene-catalyzed direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio under solvent-free conditions, Green Chem., 19, 53965402, 2017. (IF= 9.125)

[11] Zheng-Jun Wang, Xue-Yan Wang, Xia Wanga, Zhi-Wu Liang, Xinhua Xu*, Carbonylative Suzuki cross-coupling reaction catalyzed by bimetallic Pd-Pt nanodendrites under ambient CO pressure, Catal. Commun., 101, 10-14, 2017. (IF= 3.33)

[12] Zheng-Jun Wang, Xia Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu*, Ai-Jun Wang* and Zhiwu Liang, Bimetallic AuPd nanochain networks: facile synthesis and promising application in biaryl synthesis, New J. Chem., 41, 3894, 2017. (IF= 3.269

[13] Lifen Peng, Rongzhen Li, Zilong Tang*, Jingyang Chen, Rongnan Yi, Xinhua Xu*, Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosulfides via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides, Tetrahedron., 73, 3099-3105, 2017. (IF= 2.651)

[14] 毛冀川, 申玉良, 曹春雨, 舒志坚, 郑良彬, 许新华*, 利用过二硫酸盐氧化消除 2-碘双氢非那雄胺制备非那雄胺[J]. 有机化学, 2017, 37, 2430-2434.

[15] 陈锦杨, 吴小波, 易荣楠, 许新华*, 镍催化格氏试剂与二芳基乙炔偶联反应制备四取代萘[J]. 有机化学, 2017, 37, 1850-1854.

[16] Jinyang Chen, Sihai Chen, Xinhua Xu*, Zhi Tang, Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Regioselective Cleavage of Csp2S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes, J. Org. Chem., 81, 32463255, 2016. (IF= 4.849)

[17] Jing-Jing Lv, Zheng-Jun Wang, Jiu-Ju Feng, Renhua Qiu*, Ai-Jun Wanga*, Xinhua Xu*, Facile synthesis of highly active Pd-Cu nanowires catalyst through a simple wet-chemical strategy for ligand-free Suzuki cross coupling reaction, Applied Catalysis A: General., 522, 188-193, 2016. (IF= 4.339)

[18] Penghui Wang, Jinying Wang, Chak-Tong Au, Renhua Qiu*, Xinhua Xu*, Shuang-Feng Yin*, Air-stable organobismuth(V) bisperfluorooctanesulfonate as an efficient catalyst for the synthesis of N-containing compounds, Adv. Synth. Catal., 358, 1302-1308, 2016. (IF= 5.646)

[19] Sihai Chen, You Li, Jinyang Chen, Xinhua Xu*, Lebin Su, Zhi Tang, Chak-Tong Au, Renhua Qiu*, Iodine-Promoted Synthesis of Thioamides from 1,2-Dibenzylsulfane and Difurfuryl Disulfide, Synlett., 27(16), 2339-2344, 2016. (IF= 2.151)

[20] Sihai Chen, Jinyang Chen, Xinhua Xu*, Yunhua He, Rongnan Yi, Renhua Qiu*, Calix[4]arene-assisted KOH-catalyzed synthesis of O,O-dialkyl-Se-aryl phosphoroselenoates, J. Org. Chem., 818, 123-127, 2016. (IF= 2.184)

[21] Xie Wang, Longzhi Zhu, Sihai Chen, Xinhua Xu,* Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Direct C (sp3)H Arylation of Aliphatic Amides with Thiophenes, Org. Lett., 17, 52285231, 2015. (IF= 6.579)

[22] Xie Wang, Renhua Qiu,* Chunyang Yan, Vutukuri Prakash Reddy, Longzhi Zhu, Xinhua Xu,* and Shuang-Feng Yin*, Nickel-Catalyzed Direct Thiolation of C(sp3)H Bonds in Aliphatic Amides, Org. Lett., 17, 1970-1973, 2015. (IF= 6.579)

[23] Jinyang Chen, Zhi Tang, Renhua Qiu,* Yunhua He, Xie Wang, Ningbo Li, Haibo Yi,* Chak-Tong Au, Shuang-Feng Yin, and Xinhua Xu*, Cesium-Catalyzed Regioselective Synthesis of Trisubstituted Heteroatom Alkenes: A New Strategy for the Preparation of Functional Alkenes, Org. Lett., 17, 21622165, 2015. (IF= 6.579)

[24] Xiaohong Zhang, Renhua Qiu*, Congcong Zhou, Jingxing Yu, Ningbo Li, Shuangfeng Yin*, Xinhua Xu*, Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols, Tetrahedron., 71, 1011-1017, 2015. (IF= 2.651)

[25] Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Yun Chen, Shuang-Feng Yin*, Xinhua Xu*, Strong Lewis acids of air-stable binuclear triphenylantimony(V) complexes and their catalytic application in CeC bond-forming reactions, Tetrahedron., 71, 4275-4281, 2015. (IF= 2.651)

[26] Jinying Wang, Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Xinhua Xu*,Shuang-Feng Yin*, Air-stable zirconocene bis(perfluorobutanesulfonate) as a highly efficient catalyst for synthesis of N-heterocyclic compounds, J. Org. Chem., 785, 61-67, 2015. (IF= 2.184)

[27] Qizhi Dong, Ningbo Li, Renhua Qiu*, Jinying Wang, Cancheng Guo*, Xinhua Xu*, Silver-containing microemulsion as a high-efficient and recyclable catalytic system for hydration of alkynes, J. Org. Chem., 799-800, 122-127, 2015. (IF= 2.184)

[28] Zheng-Jun Wang, Jing-Jing Lv, Jiu-Ju Feng, Ningbo Li, Xinhua Xu*, Ai-Jun Wang* and Renhua Qiu*, Enhanced catalytic performance of PdPt nanodendrites for ligand-free Suzuki crosscoupling reactions, RSC Adv., 5, 2846728473, 2015. (IF= 3.108)

[29] Zheng-Jun Wang, Peng-Hui Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu,* Ai-Jun Wang,* Chak-Tong Au and Renhua Qiu*, Cu(II)@Luviset clear as recyclable catalyst for the formation of CC bond in homo-coupling of terminal alkynes, RSC Adv., 5, 9637296376, 2015. (IF= 3.108)

[30] Yanxia Nan, Wenjie Zhao, Xinhua Xu,* Chak-Tong Au and Renhua Qiu*, Synthesis, characterization and applications of selenocysteine-responsive nanoprobe based on dinitrobenzene sulfonyl-modified poly(carbonate) micelles, RSC Adv., 5, 6929969306, 2015. (IF= 3.108)

[31] You Li, Jinyang Chen, Renhua Qiu*, Xie Wang, Jinguo Long, Longzhi Zhu, Chak-Tong Au, Xinhua Xu*, Cesium hydroxide-catalyzed isomerization of terminal alkynes for the synthesis of O-allenes and N-allenes, Tetrahedron Lett., 56, 55045507, 2015. (IF= 2.193)


部分发明专利


[1] 许世镗,许新华,陈锦杨,邱仁华,散煤燃烧废气与机动车废气净化装置及污染物资源化方法,ZL 201610905643.X

[2] 梁志武,王雪艳,许新华,肖珉,一种合成炔丙胺类化合物的新方法,ZL 201711095532.8

[3] 梁志武,王正军,许新华,肖珉,石墨烯负载钯/铂催化spC-H键偶联合成1,2-二苯乙烷衍生物的方法,ZL 201711095556.3

[4] 梁志武,王正军,许新华,肖珉,一种通过sp3C-H键活化合成丙咪嗪前驱体2,2-二溴联苄的新方法,ZL 201711095713.0

[5] 许新华,张秋林,李言杰,陈雄,张青丽,含硒替加氟的内盐式硫代磷酸酯类化合物及其合成,ZL 200410047110.X

[6] 许新华,张秋林,周冰,甘油骨架上含硒的替加氟的硫代磷脂类化合物及其合成,ZL200410046925.6

[7] 许新华 刘凤伟, 齐建勇,臧中林, 李言杰,碳酸铯催化、乙腈为溶剂烷基芳醚的制备,ZL 200610031357.1

[8] 许新华度他雄胺及其中间体双键形成新方法,ZL 201710232764.7

[9]

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