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张小华

发布于:2019-02-27 星期三 08:48:25  点击数:16623

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基本信息

张小华

教授,博士导师

Email: mickyxie@hnu.edu.cn

教育背景

2002/09-2006/12,湖南大学应用化学,博士

1994/09-1997/4湖南大学,金属腐蚀与防护,硕士

 1990/09-1994/06湖南大学,金属腐蚀与防护,学士

工作履历

 2019/01-                湖南大学化学化工学院应用化学系教授  

2006/05-2018/12湖南大学化学化工学院应用化学系副教授  

 1999/06-2006/05湖南大学化学化工学院应用化学系讲师

 1997/06-1999/06湖南大学化学化工系金属腐蚀与防护教研室助教

 

研究领域

新能源材料(燃料电池、金属-空气电池、水电解、超级电容器等电极材料)制备及应用

电化学/光电化学传感分析(有机污染物、重金属离子、生物小分子、朊蛋白、DNA等的传感界面构建与检测)

金属腐蚀机理与防护技术

金属表面清洗与防护技术

 功能高分子合成与改性


科研项目

1. “基于表面分子印迹检测持久性有机污染物的电化学传感技术研究”,湖南省自然科学基金项目

2. “基于石墨烯的直接醇类燃料电池电催化剂研究”, 中央高校青年教师创新扶持项目

3.“高性能水电解槽阴极材料制备的工程化研究”,湖南大学学科交叉研究项目

4.挥发性有机物源头削减技术”,湖南省2018重点研发计划项目

5. “***表面清洗技术研究”**研究所研究项目

6. 高性能飞机表面专用清洗剂研发湖南迪清科技有限公司研发项目

学术成果

  1. Jie Tang; Biao Wang; Yanzheng Zhang; Xiaohua Zhang*; Qinghui Shen; Junfeng Qin; Song Xue; Xi Guo; Cuicui Du*; Jinhua Chen*. One-step integration of amorphous RuBx and crystalline Ru nanoparticles into B,N-doped porous carbon polyhedra for robust electrocatalytic activity towards the HER in both acidic and basic media, J. Mater. Chem. A, 2022, 10(8): 4181-4191.

  2. Biao Wang; Jie Tang; Xiaohua Zhang*; Min Hong; Haokun Yang; Xi Guo; Song Xue; Cuicui Du*; Zhixiao Liu*; Jinhua Chen*. Nitrogen doped porous carbon polyhedral supported Fe and Ni dual-metal single-atomic catalysts template-free and metal ligand-free sysnthesis with microwave-assistance and d-band center modulating for boosted ORR catalysis in zinc-air batteries, Chemical Engineering Journal, 2022, 437(1): 135295-135305.

  3. Huang, Junlin; Wang, Shiyue; Nie, Jianhang; Huang, Chuqi; Zhang, Xiaohua*; Wang, Biao; Tang, Jie; Du, Cuicui*; Liu, Zhixiao*; Chen, Jinhua*. Active site and intermediate modulation of 3D CoSe2 nanosheet array on Ni foam by Mo doping for high-efficiency overall water splitting in alkaline media, Chemical Engineering Journal, 2021, 417: 128055-128065.

  4. Yujun Xu; Cuicui Du*; Qinghui Shen; Junlin Huang; Xiaohua Zhang*; Jinhua Chen*. Well-dispersed pyrite-type RuS2 nanocrystals anchored on porous nitrogen and sulfur co-doped hollow carbon spheres for enhanced alkaline hydrogen evolution, Chemical Engineering Journal, 2021, 417: 129318.

  5. Chuqi Huang, Jianhang Nie, Zhenyang Xu, Xiaohua Zhang*, Jie Tang, Biao Wang, Junlin Huang, Cuicui Du*, Jinhua Chen*.One-step hydrothermal synthesized 3D P-MoO3/FeCo LDH heterostructure electrocatalysts on Ni foam for high-efficiency oxygen evolution electrocatalysis. International journal of hydrogen energy. 2021, 46: 12992-13000.

  6. Jianhang Nie, Min Hong, Xiaohua Zhang,* Junlin Huang, Qin Meng, Cuicui Du*and Jinhua Chen*. 3D amorphous NiFe LDH nanosheets electro-deposited on in situ grown NiCoP@NC on nickel foam for remarkably enhanced OERelectrocatalytic performance.Dalton Trans., 2020, 49, 4896–4903.

  7. Min Hong; Jianhang Nie; Xiaohua Zhang*; Pengfei Zhang; Qin Meng; Junlin Huang; Zhenyang Xu; Cuicui Du*; Jinhua Chen* ; Facile solution synthesis of FeNx atom clusters supported on nitrogenenriched graphene carbon aerogels with superb electrocatalytic performance toward the oxygen reduction reaction, Journ al of Materials Chemistry A, 2019, 7(44): 25557-25566. 

  8. Zhigang Jiang, Jincan Ren,Yapeng Li, Xiaohua Zhang,* Pengfei Zhang, Junlin Huang, Cuicui Du* and Jinhua Chen*. Low-cost high-performance hydrogen evolution electrocatalysts based on Pt-CoP polyhedra with low Pt loading in both alkaline and neutral media.Dalton Trans., 2019, 48, 8920.

  9. Yanmei Li, Leixia Meng, Kang Zou, Xiaohua Zhang*, Jinhua Chen*. A novel photoelectrochemical immunosensor for prion protein based on CdTe quantum dots and glucose oxidase. Journal of Electroanalytical Chemistry. 2018,829 : 51 -58.

  10. Xiaoxia Yan, Junjing Li, Ruiying Yang, Yanmei Li, Xiaohua Zhang*, Jinhua Chen*. A new photoelectrochemical aptasensor for prion assay based on cyclodextrin and Rhodamine B. Sensors and Actuators B: Chemical. 2018, 255:2187–2193.

  11. Junjing LiXiaoxia YanXiaoyu LiXiaohua Zhang*Jinhua Chen*. A new electrochemical immunosensor for sensitive detection of prion based on Prussian blue analogue. Talanta. 2018, 179: 726-733.

  12. Erhu Xiong, Zhenzhen Li, Xiaohua Zhang*, Jiawan Zhou, Xiaoxia Yan, Yunqing Liu, Jinhua Chen*.Triple-Helix Molecular Switch Electrochemical Ratiometric Biosensor for Ultrasensitive Detection of Nucleic Acids. Analytical Chemistry. 2017, 89: 8830−8835.

  13. Yunqing Liu, Erhu Xiong, Xiaoyu Li, Junjing Li, Xiaohua Zhang*, Jinhua Chen*. Sensitive electrochemical assay of alkaline phosphatase activity based on TdT-mediated hemin/G-quadruplex DNAzyme nanowires for signal amplification. Biosensors and Bioelectronics. 2017, 87:970-975.

  14. Erhu Xiong, Xiaoxia Yan, Xiaohua Zhang*, Yunqing Liu, Jiawan Zhou, Jinhua Chen*. Exonuclease III–assisted cascade signal amplification strategy for label-free and ultrasensitive electrochemical detection of nucleic acids. Biosensors and Bioelectronics. 2017, 87: 732-736.

  15. Xiaoyu Li, Junjing Li, Yunqing Liu, Xiaohua Zhang*, Jinhua Chen*. A sensitive electrochemical immunosensor for prion detection based on poly-β-cyclodextrin/gold nanoparticles/glassy carbon electrode. Sensors and Actuators B: Chemical.2017,250: 1-7.

  16. Peng Yu, Yunqing Liu, Xiaohua Zhang*, Jiawan Zhou, Erhu Xiong, Xiaoyu Li, Jinhua Chen*. A novel electrochemical aptasensor for bisphenol A assay based on triple-signaling strategy. Biosensors and Bioelectronics. 2016, 79:22-28.

  17. Peng Yu, Xiaohua Zhang*, Erhu Xiong, Jiawan Zhou, Xiaoyu Li, Jinhua Chen*. A label–free and cascaded dual–signaling amplified electrochemical aptasensing platform for sensitive prion assay. Biosensors and Bioelectronics. 2016, 85:471-478.

  18. Wenyang Wang, Kanghua Jiang, Xiaohua Zhang*, Jinhua Chen*. A high-performance bioanode based on a nitrogendoped short tubular carbon loaded Au nanoparticle co-immobilized mediator and glucose oxidase for glucose/O2 biofuel cells. RSC Adv., 2016, 6, 29142–29148

  19. Erhu XiongYunqing LiuJiawan ZhouPeng Yu, Xiaohua Zhang*, Jinhua Chen*An electrochemical biosensor for sensitivedetection of Hg2+ based on exonuclease III-assistedtarget recycling and hybridization chain reaction amplification strategiesAnalytical Methods2016(8)2106-2111

  20. Li Li, Chunxia Tian, Junshuai Yang, Xiaohua Zhang*, Jinhua Chen*.One-pot synthesis of PtRh/b-CD-CNTs for methanol oxidation. International journal of hydrogen energy 40 ( 2015 ) 14866-14874.

  21. Peng YuYunqing LiuJiawan ZhouErhu XiongXiaoyu Li, XiaohuaZhang*Jinhua Chen*A novel electrochemical aptasensor for bisphenol A assay based on triple-signaling strategyBiosensors and Bioelectronics20157922-28.

  22. Li Li, Xin Guo, Fei Hao, Xiaohua Zhang*, Jinhua Chen*. Solid-state grinding/low-temperature calcining synthesis of carbon coated MnO2 nanorods and their electrochemical capacitive property. New J. Chem., 2015, 39, 4731-4736.

  23. LiangWu Yue YaoZhenzhen LiXiaohua Zhang* Jinhua Chen *. A new amplified impedimetric aptasensor based on the electron transfer ability of Au nanoparticles and their affinity with aptamerJournal of Electroanalytical Chemistry2015757243-249

  24. Li Li, Chunxia Tian, Junshuai Yang, Xiaohua Zhang*, Jinhua Chen*. One-pot synthesis of PtRh/b-CD-CNTs for methanol oxidation. International  journal of hydrogen energy. 2015, 40:14866-14874.

  25. 李丽§, 何小丽§, 覃涛, 戴富涛, 张小华* 陈金华*. 双牺牲模板法制备一维管状Pt-Mn3O4-C复合物及其优越的甲醇电催化氧化性能. Acta Phys. -Chim. Sin. 2015, 31 (5), 927-932.

  26. Fei Hao, Li Li, Xiaohua Zhang*, Jinhua Chen. Synthesis and electrochemical capacitive properties of nitrogen-doped porous carbon micropolyhedra by direct carbonization of zeolitic imidazolate framework-11. Materials Research Bulletin 2015,66 :88–95.

  27. Xia ZhangLiang WuJiawan ZhouXiaohua Zhang*, Jinhua Chen*A new ratiometric electrochemical sensor for sensitive detection of bisphenol A based on poly-b-cyclodextrin/electroreduced graphene modified glassy carbon electrodeJournal of Electroanalytical Chemistry201574297-103

  28. Xin Guo, Li Li, Xiaohua Zhang,* Jinhua Chen*. Platinum Nanoparticles Encapsulated in Nitrogen-Doped Mesoporous Carbons as Methanol-Tolerant Oxygen Reduction Electrocatalysts. ChemElectroChem 2015, 2, 404-411.

  29. Longfei Sun, Wenyang WangXiaohua Zhang*, Jinhua Chen*, Carbon nanotube–ionic liquid composite gel based high-performance bioanode for glucose/O2 biofuel cellsAnal. Methods201575060-5066

  30. Peng Yu Jiawan ZhouLiang WuErhu Xiong, Xiaohua Zhang*, Jinhua Chen*A ratiometric electrochemical aptasensor for sensitive detection of protein based on aptamer–target–aptamer sandwich structureJournal of Electroanalytical Chemistry201473261-65

  31. Erhu Xiong Liang WuJiawan ZhouPeng YuXiaohua Zhang*, Jinhua Chen*. A ratiometric electrochemical biosensor for sensitive detection of Hg2+ based on thymine–Hg2+–thymine structureAnalytica Chimica Acta A2014853242-248

  32. Liang Wu ErhuXiongYueYaoXiaZhangXiaohua Zhang*, Jinhua Chen*A new electrochemical aptasensor based on electrocatalytic property of grapheme toward ascorbic acid oxidationTalanta2014134699-704

  33. Rui ChengQiong ZouChunhui XiaoLongfei Sun, Xiaohua Zhang*, Jinhua Chen*Template Synthesis of Nitrogen-Doped Short Tubular Carbons with Big Inner Diameter and their Application in Electrochemical SensingBull. Korean Chem. Soc., 2014, 35(8): 2423-2430

  34. Gangbing Zhu, Xiaohua Zhang*, Jinhua Chen*. Sensitive electrochemical sensor of anthracene-9-carbonxylic acid using an electropolymerized film modified glassy carbon electrode. Analytical Methods, 5, 1881-1885, 2013.

  35. ZHANG Xiao-Hua*, ZHONG Jin-Di, YU Ya-Ming, ZHANG Yun-Song, LIU Bo, CHEN Jin-Hua*. Well-Dispersed Platinum Nanoparticles Supported on Nitrogen-Doped Hollow Carbon Microspheres for Oxygen-Reduction Reaction. Acta Phys.-Chim. Sin. 29 (6), 1297-1304, 2013.

  36. 高磊, 廖奕, 张小华*, 陈金华*. 聚苯胺纳米刺/掺氮空心碳球复合材料的制备及电容性能. 高等学校化学学报, 34(12), 2845 -2849, 2013.

  37. Jiayue Ma, Yunsong Zhang, Xiaohua Zhang*, Gangbing Zhu, Bo Liu, Jinhua Chen. Sensitive electrochemical detection of nitrobenzene based on macro-/meso-porous carbon materials modified glassy carbon electrode. Talanta, 88, 696-700, 2012.

  38. Yi Liao, Lei Gao, Xiaohua Zhang*, Jinhua Chen. Nitrogen-doped hollow carbon spheres with enhanced electrochemical capacitive properties. Materials Research Bulletin, 47, 1625–1629, 2012.

  39. Juan Liu, Xiaohua Zhang*, Haili Pang, Bo Liu, Qiong Zou, Jinhua Chen*. High-performance bioanode based on the composite of CNTs-immobilized mediator and silk film-immobilized glucose oxidase for glucose/O2 biofuel cells. Biosensors and Bioelectronics, 31, 170– 175, 2012.